This restricts the application of the classical continuum theory to the nanoflows. So far, the viscosity of fluids in nanoconfinement on a scale comparable to the molecular diameter is seldom explored owing to the extremely small scale on which the transport properties are difficult to be captured by experiments and the intrinsic limitations of the existing computational methods in the MD simulations. The previous results have identified that the water viscosity relies on the temperature and the characteristic length of the nanochannel. In classical continuum theory, the viscosity is an essential transport property and thereby has been extensively measured and computed. Hence, many researches focused on the unique feature of the confined fluid and its relationship with the continuum fluid. The previous studies have revealed that the flow behavior of water at the nanoscale strongly depends on the characteristic length of nanochannel, which implies that the classical continuum theory for the macroscopic fluid may be no longer applicable for the fluid confined in nanochannels. It is a significant topic for studying and designing the nanodevices such as the nanochannel for drug delivery and the membrane for water desalination. Water conduction through single-walled carbon nanotubes (SWCNTs) has been paid much attention in recent years. The present results should be instructive for understanding the coupling effect of the size and the temperature at the nanoscale. The results of the relative amount of the hydrogen bonds exhibit similar profiles with the curves of the relative viscosity. To demonstrate the rationality of the calculated relative viscosity, the relative amount of the hydrogen bonds of water confined in SWCNTs is also computed. Based on the computational results, a fitting formula is proposed to calculate the size- and temperature- dependent water viscosity, which is useful for the computation on the nanoflow. The results suggest that the relative viscosity of the confined water increases with increasing diameter and temperature, whereas the size-dependent trend of the relative viscosity is almost independent of the temperature. The influences of the diameter (size) of single-walled carbon nanotubes (SWCNTs) and the temperature on the viscosity of water confined in SWCNTs are investigated by an "Eyring-MD" (molecular dynamics) method.
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